This technology provides a novel approach to fabricating hexagonal ε-(InxGa1-x)2O3 thin films on AlN/Sapphire templates by carefully controlling pulsed laser deposition parameters such as heater temperature, oxygen pressure, and laser settings. It overcomes challenges like orthorhombic phase formation and indium desorption, enabling the production of device-grade, single-crystal epitaxial films. Comprehensive characterization confirms the material’s crystal structure, composition, and optical properties, demonstrating repeatable and controllable fabrication essential for advanced electronic applications.